Sunday, August 5, 2012

6. Tests of Chemical Equilibrium


Test #1
Name of Student ________________                                                           Class : XI

Q.1 Explain the following term
i )Reversible reaction  ii)   Equilibrium constant
 iii) Solubility product iv) Law of Mass Action
 v) Le- Chatelier principle
Q.2 How is Kc used to predict the direction of a reversible reaction?
Q.3 In chemical reaction                     PCl5      ↔    PCl3                 + Cl2
Calculate the mole of chlorine produce at equilibrium when 1 mole of PCl5 is heated at 2500c in a vessel of capacity 10 dm3 (Kc for the reaction is 0 .041)
Q.4          5 moles of acetic acid and 1.5 moles of ethyl alcohol were reacted at a certain temperature. At equilibrium, 1 mole of ethyl acetate was present in 1 dm3 of the equilibrium mixture. Calculate the equilibrium constant Kc.

CH3COOH + C2H5OH            ↔                   CH3COOC2H5 + H2O


Test #2
Name of Student ________________                                               Class :XI  

Q.1  State and explain Law of Mass Action and derive the  equilibrium constant expression for the general equilibrium reaction :
                                    mA    + nB     ↔    xC       +   yD
Q.2  For reaction
                        N  +  3H2 ↔= 2NH3
The equilibrium mixture contain  .25 M nitrogen  .15 M  hydrogen gas at 250 c. Calculate the concentration of NH3 gas when Kc =9.6 .The volume of the container is 1dm3.  
Q.3  For the reaction    H2   +   I2 ↔  2HI
Kc is     49 . Calculate the concentration of HI at equilibrium when initial one mole of H2 is mixed with
one more of I2 in one liter flask .
Q.4    The solubility of Mg(OH)2 at 25°C is 0.00764 gm/dm3.
What is the solubility product of Mg(OH)2?        Mg(OH)2 ↔ Mg++ + 2OH-

Test #3
Name of Student ________________                                               Class :XI


Q.1State and explain Le-Chatlelier principle. Discuss the condition to increase
the yield of NH3 in Haber’s process.
Q.2 Will PbCrO4 precipitate from a solution prepared by mixing 200 cm3 of 2.5 x 10-4 M Pb(NO3)2 and 600 cm3 of 1.5 x 10-8 M of  K2CrO4?  (K(sp) of PbCrO4 = 1.5 x 10-14 )
Q.3 The equilibrium constant for the reaction    N2 + O2 ↔ 2NO
at 20000C is 0.1. Calculate the equilibrium concentration of the reactants and product when the initial concentration of N2 and O2 are 10 mole/dm3
Q.4 At a certain temperature, an equilibrium mixture contains 0.4 mole H2, 0.4 mole I2 and 1 mole of HI. The volume of the reacting vessel is 4 dm3. Find out the equilibrium constant  Kc.
                   H2 + I2      ↔        2HI

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