Friday, February 3, 2012

CRQs AND ERQs


Chemical Equilibrium
SLO’s
Types
Questions
Marks
















CRQ’s

Q. Define the following
 i) Chemical equilibrium   ii) Reversible reaction
iii) Irreversible reaction 



Q Write the equilibrium  expression of the following
            i)   N2 + 3H2↔2NH3
            ii)  H2 + I2 ↔ 2 HI


Q. Derive the Equilibrium expression of the following
            mA  + nB ↔ x C + y D
            where the molar concentrations of A ,B ,C and D  are respectively          [A],[B],  [C]    and [D]           



Q. Derive the Equilibrium expression of the following
            mA  + nB ↔ x C + y D
            where the Partial pressures   of A ,B ,C and D  are respectively          PA, PB  , PC             and PD



Q. Derive the Equilibrium expression of the following
            mA  + nB ↔ x C + y D
            where the number  of moles  A ,B ,C and D  are respectively    m , n , x  and y



Q . Discuss the effect of temperature on chemical        
      equilibrium state of the following 
            A↔B      ∆H=negative



Q . Discuss the effect of temperature on chemical        
      equilibrium state of the following 
            A↔B      ∆H= Positive



Q . Discuss the effect of pressure  on chemical        
      equilibrium state of the following 
            A2 + 3B2 ↔2AB3     


Q. Predict the condition of equilibrium sate  for the following reaction
       N2 + 3H2↔2NH3
 When the equilibrium mixture contain
 0.25 M of N2 , 0.25 M of  H2 and  0.12M NH3.
The equilibrium constant is                                           




ERQ’s
 
Discuss the Le-Chatlerier principle on different example


State and explain the Le-Chaterier  Principle


State Le- Chatlerier Principle .Apply the principle on
the  following reaction
i) 2SO2   +  O2  ↔ 2SO3                                     ∆H=Negative




CRQ’s

Define the following
i)  Solubility product  ii) Common ion  effect


State and explain the solubility product  of AgCl


Write two main difference between solubility and solubility product



ERQ’s
Discuss the application of common ion effect











Tuesday, December 27, 2011

Answer Sheet

       Answer Sheet
1.   B
2.   B
3.   B
4.   C
5.   C
6.   Incorrect options
7.   A
8.   A
9.   B
10.         C
11.         C
12.         A
13.         C
14.         B
15.         B
16.         C
17.         A
18.         C
19.         A
20.         A
21.         C
22.         C
23.         B
24.         B
25.         B
26.         A
27.         A
28.         A
29.         A
30.         C
31.         Azimuthal
32.         Pauli’s Exclusion Principle
33.         Decreases
34.         Same
35.         Increases
36.         High
37.         -273.16°C
38.         High
39.         Greater
40.         Ionization of gas in a discharge tube
41.         2 gm of nitrogen
42.         Line Spectrum
43.         P-P
44.         CO2
45.         shape of an orbital
46.         Empirical Formula
47.         Molecular Formula
48.         6.02 x 1023
49.         C2H6
50.         Indicates the simplest ratio of the atoms
51.         1.204 x 1024
52.         6.02 x 1023
53.         Five
54.         12
55.         Molecular
56.         6.02 x 1023
57.         Lighter than
58.         5.56
59.         Neutral
60.         Ionic
61.         342
62.         Boyle
63.         Vary inversely as the pressure
64.         Charles
65.         Absolute Zero
66.         High- low
67.         Contraction
68.         0°C
69.         0 K
70.         32°F
71.         -273°C
72.         Collisions
73.         373 K
74.         Pressure and volume
75.         temperature and volume
76.         Avogadro’s Law
77.         373 K
78.         Ideal gases
79.         More readily
80.         Bond Energy
81.         Question missing
82.         Polar Covalent
83.         less than 1.7
84.         H-F
85.         Ionic
86.         Covalent
87.         109.5°
88.         Stronger
89.         Tetrahedral
90.         Tetrahedral
91.         Non polar
92.         Polar
93.         Non polar
94.         Question missing
95.         Sp3
96.         Sp2
97.         Sp
98.         Two
99.         One
100.    Molecular
101.    Paramagnetic
102.    Hydrogen bond
103.    HF
104.    Tetrahedral
105.    Sigma bond
106.    Bond energy
107.    __________
108.    __________
109.    __________